Atomic Mechanisms of Crystallization in Nano-Sized Metallic Glasses

نویسندگان

چکیده

Understanding crystallization mechanisms in nano-sized metallic glasses (MGs) is important to the manufacturing and application of these new nanomaterials that possess a unique combination structural functional properties. Due two-dimensional projections limited spatial and/or temporal resolutions experiments, significant questions (e.g., whether nucleation takes place on free surface or near-surface layer) regarding this subject remain under debate. Here, we address outstanding using molecular dynamics simulations MG nanorods together with atomistic visualization data analysis. We show MGs predominantly by converting high-energy liquid lower-energy crystal (the most close-packed atomic plane). This true for all different diameters studied. On other hand, apparent growth mode (inward/radial, lateral longitudinal) resulting grain structure are more dependent nanorod diameter. For relatively big diameter nanorod, overall rate does not differ much among three directions grains approximately semispherical. small diameters, appear grow longitudinal direction some may form long single-crystal segments along length nanorod. The reasons difference discussed. study provides direct insights into MGs, which can facilitate advanced materials.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Crystallization Kinetics of Metallic Glasses

Metallic glasses are kinetically metastable materials. Metallic glass is defined as “A liquid, which has been cooled into a state of rigidity without crystallizing”. Properties of metallic glasses differ form non metallic glasses. Ordinary glasses are made up of silica while metallic glasses are made of alloy metals. Ordinary glasses are transparent whereas metallic glasses are opaque. In ordin...

متن کامل

Microstructure of fragile metallic glasses inferred from ultrasound-accelerated crystallization in Pd-based metallic glasses.

By utilizing ultrasonic annealing at a temperature below (or near) the glass transition temperature Tg, we revealed a microstructural pattern of a partially crystallized Pd-based metallic glass with a high-resolution electron microscopy. On the basis of the observed microstructure, we inferred a plausible microstructural model of fragile metallic glasses composed of strongly bonded regions surr...

متن کامل

Atomic Dynamics in Metallic Liquids and Glasses

How atoms move in metallic glasses and liquids is an important question in discussing atomic transport, glass formation, structural relaxation and other properties of metallic glasses. While the concept of free-volume has long been used in describing atomic transport, computer simulations and isotope measurements have shown that atomic transport occurs by a much more collective process than ass...

متن کامل

Fractal atomic-level percolation in metallic glasses.

Metallic glasses are metallic alloys that exhibit exotic material properties. They may have fractal structures at the atomic level, but a physical mechanism for their organization without ordering has not been identified. We demonstrated a crossover between fractal short-range (<2 atomic diameters) and homogeneous long-range structures using in situ x-ray diffraction, tomography, and molecular ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Crystals

سال: 2022

ISSN: ['2073-4352']

DOI: https://doi.org/10.3390/cryst13010032